IIT JAM Chemistry Syllabus 2013
IIT JAM 2013 Chemistry Syllabus
Physical Chemistry
Basic Mathematical Concepts : Functions, maxima and minima, integrals, ordinary differential equations, vectors and matrices, determinants, elementary statistics and probability theory.
Atomic Structure : Fundamental particles. Bohr’s theory of hydrogen atom; Wave – particle duality; Uncertainty principles; Schrodinger’s wave equation; Quantum numbers, shapes of orbitals; Hund’s rule and Pauli’s exclusion principle, electronic configuration of simple homonuclear diatomic molecules.
Theory of Gases : Equation of state of ideal and nonideal ( van der Waals ) gases, Kinetic theory of gases. Maxwell-Boltzmann distribution law; equipartition of energy. Solid state: Crystals, crystal systems, X-rays, NaCl and Kcl structures, close packing, atomic and ionic radii, radius ratio rules, lattice energy, Born-Haber cycle, isomorphism, heat capacity of solids.
Chemical Thermodynamics : Reversible and irreversible processes; First law and its application to ideal and non – ideal gases; Thermochemistry; Second law; Entropy and free energy, Criteria for spontaneity.
Chemical and Phase Equilibria : Law of mass action; Kp, Kc, Kx and Kn; Effect of temperature on K; Ionic equilibria in solutions; pH and buffer solutions; Hydrolysis; Solubility product; Phase equilibria – Phase rule and its application to one – component and two – component systems; Colligative properties.
Electrochemistry : Conductance and its applications; Transport number; Galvanic cells; EMF and Free energy; Concentration cells with and without transport; Polarography; Concentration cells with and without transport; Debey-Huckel-Onsagar theory of strong electrolytes.
Chemical Kinetics : Reactions of various order, Arrhenius equation, Collision theory; Theory of absolute reaction rate; Chain reactions – Normal and branched chain reactions; Enzyme kinetics; photochemical processes; Catalysis.
Adsorption : Gibbs adsorption equation, adsorption isotherm, types of adsorption, surface area of adsorbents, surface films on liquids.
Organic Chemistry
Basic Concepts in Organic Chemistry and Stereochemistry : Isomerism and nomenclature, electronic ( resonance and inductive ) effects. Optical isomerism in compounds containing one and two asymmetric centers, designation of absolute configuration, conformations of cyclohexanes.
Organic Reaction Mechanism and Synthetic Applications : Chemistry reactive intermediates, carbine, nitrene, benzyne, Hofmann-Curtius-Lossen rearrangement, Wolf rearrangement, Simmons-Smith reaction, Reimer- Tiemann reaction, Michael reaction, Darzens reaction, Witting reaction, McMurry reaction. Pinacol-pinacolone, Favorskii, benzilic acid rearrangement, dienonc-phenol rearrangement, Bayer-Villeger reaction. Oxidation and reduction reactions in organic chemistry. Organometallic reagents in organic synthesis ( Grignard and organocopper ). Diels-Alder reaction, Sigmatropic reactions.
Qualitative Organic Analysis: Functional group interconversions, structural problems using chemical reactions, identification of functional groups by chemical tests, elementary 1H NMR and IR spectroscopy as a tool for structural elucidation.
Natural Products Chemistry : Introductory chemistry of alkaloids, terpenes, carbohydrates, amino acids, peptides and nucleic acids.
Heterocyclic Chemistry : Furans, thiophenes, pyrrols and pyridines.
Qualitative Organic Analysis : Functional group interconversions, structural problems using chemical reactions, identification of functional groups by chemical tests.
Inorganic Chemistry
Periodic Table : Periodic classification of elements and periodicity in properties; general methods of isolation and purification of elements.
Chemical Bonding and Shapes of Compounds : Types of bonding; VSEPR theory and shapes of molecules; hybridization; dipole moment; ionic solids; structure of NaCl, CsCl, diamond and graphite; lattice energy.
Main Group Elements ( s and p blocks ) : Chemistry with emphasis on group relationship and gradation in properties; structure of electron deficient compounds of main group elements and application of main group elements.
Transition Metals ( d block ) : Characteristics of 3d elements; oxide, hydroxide and salts of first row metals; coordination complexes; VB and Crystal Field theoretical approaches for structure, colour and magnetic properties of metal complexes. Ligands with back bonding capabilities; molecular orbital theory approaches to explain bonding in metal – carbonyl and metal – phosphine complexes.
Analytical Chemistry : Principles of qualitative and quantitative analysis; acid – base, oxidation – reduction and EDTA and precipitation reactions; use of indicators; use of organic reagents in inorganic analysis; radioactivity; nuclear reactions; applications of isotopes.
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